I have spending a good time in googling around for solution to make the label and value to show on the chart by default instead of mouse over tooltips popup.

Finally I found this code from jsfiddle by Suhaib Janjua which work! A big thanks to him.

Here’s the code which tested to work in AdminLTE V.3.0.2

// Show tooltips always even the stats are zero

Chart.pluginService.register({
  beforeRender: function(chart) {
    if (chart.config.options.showAllTooltips) {
      // create an array of tooltips
      // we can't use the chart tooltip because there is only one tooltip per chart
      chart.pluginTooltips = [];
      chart.config.data.datasets.forEach(function(dataset, i) {
        chart.getDatasetMeta(i).data.forEach(function(sector, j) {
          chart.pluginTooltips.push(new Chart.Tooltip({
            _chart: chart.chart,
            _chartInstance: chart,
            _data: chart.data,
            _options: chart.options.tooltips,
            _active: [sector]
          }, chart));
        });
      });

      // turn off normal tooltips
      chart.options.tooltips.enabled = false;
    }
  },
  afterDraw: function(chart, easing) {
    if (chart.config.options.showAllTooltips) {
      // we don't want the permanent tooltips to animate, so don't do anything till the animation runs atleast once
      if (!chart.allTooltipsOnce) {
        if (easing !== 1)
          return;
        chart.allTooltipsOnce = true;
      }

      // turn on tooltips
      chart.options.tooltips.enabled = true;
      Chart.helpers.each(chart.pluginTooltips, function(tooltip) {
        tooltip.initialize();
        tooltip.update();
        // we don't actually need this since we are not animating tooltips
        tooltip.pivot();
        tooltip.transition(easing).draw();
      });
      chart.options.tooltips.enabled = false;
    }
  }
});

// Show tooltips always even the stats are zero


var canvas = $('#myChart').get(0).getContext('2d');
var doughnutChart = new Chart(canvas, {
  type: 'doughnut',
  data: {
    labels: [
      "Success",
      "Failure"
    ],
    datasets: [{
      data: [45, 9],
      backgroundColor: [
        "#1ABC9C",
        "#566573"
      ],
      hoverBackgroundColor: [
        "#148F77",
        "#273746"
      ]
    }]
  },
  options: {
    // In options, just use the following line to show all the tooltips
    showAllTooltips: true
  }
});